What are the similarities and differences between the lanthanides series and the actinide series?

1 Answer
Apr 11, 2018

Mainly, the actinides have bigger orbitals, but their 5f orbitals are more radially compact compared to the 4f orbitals of the lanthanides, so there are more so-called "Aufbau exceptions" among the actinides.

Other factors are listed below, like electronegativities and oxidation states.


Here it is in a table... "L""n" = "lanthanide", "An" = "actinide".

" "" "" "ul(" "" "" ""Electroneg."" ""Atomic Radius"" "" ""Oxid. States"" ""Exceptions")
"L""n"color(white)(..........)"Lower"" "" "" "" ""Smaller"" "" "" "" ""+3 usually"" "" "3
"An"color(white)(.........)"Variable"" "" "" ""Larger"" "" "" "" "color(white)(.)"+3 to +7"" "" "" "6

  • The electronegativities of the lanthanides are lower than for the actinides, but also more consistent. The actinide electronegativities are quite diverse. This is a graph made from data in Tro:

  • The atomic radii of the actinides is bigger simply due to a new quantum level as expected.

  • The actinides also achieve more diverse oxidation states due to higher d orbital participation. Thus, their oxidation states range from +3 to +7. The +3 oxidation state is somewhat common among them, but less so than among the lanthanides.

Lanthanides:

Actinides:

  • Lastly, there are more electron configuration exceptions among the actinides, due to that higher 6d participation.

The exceptions are "La", "Ce", and "Gd" for the lanthanides, and "Ac", "Th", "Pa", "U", "Np", and "Cm" for the actinides. In red are the exceptions.

color(white)([(color(red)(La),(color(red)([Xe] 6s^2 5d^1)),color(black)(Tb),(color(black)([Xe] 6s^2 4f^9))),(color(red)(Ce),(color(red)([Xe] 6s^2 4f^1 5d^1)),color(black)(Dy),(color(black)([Xe] 6s^2 4f^10))),(color(black)(Pr),(color(black)([Xe] 6s^2 4f^3)),color(black)(Ho),(color(black)([Xe] 6s^2 4f^11))),(color(black)(Nd),(color(black)([Xe] 6s^2 4f^4)),color(black)(Er),(color(black)([Xe] 6s^2 4f^12))),(color(black)(Pm),(color(black)([Xe] 6s^2 4f^5)),color(black)(Tm),(color(black)([Xe] 6s^2 4f^13))),(color(black)(Sm),(color(black)([Xe] 6s^2 4f^6)),color(black)(Yb),(color(black)([Xe] 6s^2 4f^14))),(color(black)(Eu),(color(black)([Xe] 6s^2 4f^7)),color(black)(Lu),(color(black)([Xe] 6s^2 4f^14 5d^1))),(color(red)(Gd),(color(red)([Xe] 6s^2 4f^7 5d^1)),"","")])

color(white)([(color(red)(Ac),(color(red)([Rn] 7s^2 6d^1)),color(black)(Bk),(color(black)([Rn] 7s^2 5f^9))),(color(red)(Th),(color(red)([Rn] 7s^2 6d^2)),color(black)(Cf),(color(black)([Rn] 7s^2 5f^10))),(color(red)(Pa),(color(red)([Rn] 7s^2 5f^2 6d^1)),color(black)(Es),(color(black)([Rn] 7s^2 5f^11))),(color(red)(U),(color(red)([Rn] 7s^2 5f^3 6d^1)),color(black)(Fm),(color(black)([Rn] 7s^2 5f^12))),(color(red)(Np),(color(red)([Rn] 7s^2 5f^4 6d^1)),color(black)(Md),(color(black)([Rn] 7s^2 5f^13))),(color(black)(Pu),(color(black)([Rn] 7s^2 5f^6)),color(black)(No),(color(black)([Rn] 7s^2 5f^14))),(color(black)(Am),(color(black)([Rn] 7s^2 5f^7)),color(black)(Lr),(color(black)([Rn] 7s^2 5f^14 6d^1))),(color(red)(Cm),(color(red)([Rn] 7s^2 5f^7 6d^1)),"","")])

I cover those in detail here.