HCl is a polar molecule, how come the intermolecular forces among its molecules consist of London dispersion force besides dipole dipole attraction ? Thank for answering.

1 Answer
Sep 26, 2017

Dispersion forces exist by virtue of having electrons. Electron density instantaneously changes at each moment in time, forming weak temporary dipoles, which we term dispersion interactions between particles.


All molecules and atoms have London dispersion (i.e. van der Waals) forces. With #"HCl"#, a polar molecule, all we say is that the predominant intermolecular force is dipole dipole interaction.

#stackrel(delta^+)"H"-stackrel(delta^-)"Cl"#

Even though #"HCl"# has dispersion forces, they are overshadowed by dipole-dipole by far. If they were not, then #"HCl"# would not be soluble in water...

Since water hydrogen-bonds, the most fair trade in interaction energy would be from strong dipole-dipole interactions, not weak dispersion.

Or if you prefer, the saying, "like dissolves like" results in the same conclusion.