If I want the change in Gibbs's free energy for the reverse reaction, do I also take the reciprocal?
1 Answer
No, it's not. It's just the opposite sign.
Try not to confuse the properties of the equilibrium constant with a state function like
#ul"Equilibrium Constants"# For some equilibrium constant
#K# , an altered equilibrium constant#K'# due to modifying a reaction would be as follows.
- Reversed reactions have
#K' = K^(-1)# .- Reactions with stoichiometric coefficients scaled by a constant
#c# have#K' = K^c# , i.e. the whole thing is raised by that constant.For some reaction
#nu_A A + nu_B B -> nu_C C + nu_D D# ,if you instead have
#2nu_C C + 2nu_D D -> 2nu_A A + 2nu_B B# ,what you end up with is
#K' = (K^2)^(-1) = K^(-2) = 1/K^2# .
#ul"State Functions"# For the change in some state function
#DeltaY# (such as enthalpy, entropy, volume, temperature, pressure, etc), the altered change in the state function#DeltaY'# would be as follows.
- Reversed reactions have
#DeltaY' = -DeltaY# .- Reactions with stoichiometric coefficients scaled by a constant
#c# have#DeltaY' = cDeltaY# , i.e. you just multiply by that constant.For some reaction
#nu_A A + nu_B B -> nu_C C + nu_D D# ,if you instead have
#2nu_C C + 2nu_D D -> 2nu_A A + 2nu_B B# ,what you end up with is
#DeltaY' = -2DeltaY# .