Show that for a closed loop in a Carnot engine, the energy is conserved in the heat flow at a certain temperature in each reservoir, i.e. show that #q_H/T_H + q_C/T_C = 0#?
1 Answer
A Carnot engine can be represented as follows:
Let me expand what is on the right.
#ointdS = int_(a)^(a) dS = S_i - S_i = 0# ,since
#S# is entropy, which is a state function describing the amount of energy dispersal, and a closed integral, "#oint# ", indicates that the initial and final states are identical (hence,#DeltaS = S_i - S_i = 0# ).
By definition,
#dS = (deltaq_(rev))/T# ,where
#q_(rev)# is reversible heat flow, i.e. heat flow applied in an infinitesimally slow manner, such that the system has the chance to re-equilibrate the entire time the heat is applied.
The hot reservoir, with temperature
If this heat transfer is exact, i.e. if we have conservation of energy and the heat is transferred reversibly, then:
#oint(deltaq_(rev))/T = ointdS = int (deltaq_H)/(T_H) + int (deltaq_C)/(T_C) = 0#
Hence, integrating with respect to the heat flow in from/to each reservoir, we have:
#color(blue)(q_H/T_H + q_C/T_C = 0)#