Explain a single-replacement reaction with an example?

1 Answer
Jan 12, 2016

Let's just take this reaction as an example. Plop some aluminum solid into concentrated aqueous hydrochloric acid to get out aqueous aluminum chloride and hydrogen gas.

#2"Al"(s) + 6"HCl"(aq) -> 2"AlCl"_3(aq) + 3"H"_2(g)#

You can see that:

  • Typically, you would see single replacement reactions in the form #\mathbf(A + BC -> AC + B)#, and this matches that format. You should see #A# "swap" with #B#. (Technically, #C# came onto #A#, but, anyways...)
  • One reactant is in its elemental state (aluminum), and one product is in its elemental state (hydrogen). Hence, a "solo" reactant "swapped" with a "coupled" component of another reactant, as you would expect single replacement reactions to be.
  • The subscript on the anion (chloride) changed. Hence, it now is with a different cation and a different distribution of the same number of chlorides was required to balance charges. (Compare the charge of aluminum cation with that of a hydrogen cation.)